Buildup of vibron-mediated electron correlations in molecular junctions

Electron transport in molecular wire junctions.

Molecular conductance junctions are structures in which single molecules or small groups of molecules conduct electrical current between two electrodes. In such junctions, the connection between the molecule and the electrodes greatly affects the current-voltage characteristics. Despite several experimental and theoretical advances, including the understanding of simple systems, there is still ...

Boosting spin-caloritronic effects by attractive correlations in molecular junctions

In nanoscopic systems quantum confinement and interference can lead to an enhancement of thermoelectric properties as compared to conventional bulk materials. For nanostructures, such as molecules or quantum dots coupled to external leads, the thermoelectric figure of merit can reach or even exceed unity. Moreover, in the presence of external magnetic field or when the leads are ferromagnetic, ...

Current hysteresis and memory effect in a molecular quantum dot with strong electron-vibron interaction

Electron-vibron coupling in suspended carbon nanotube quantum dots

Motivated by recent experiments, we investigate the electron-vibron coupling in suspended carbon nanotube quantum dots, starting with the electron-phonon coupling of the underlying graphene layer. We show that the coupling strength depends sensitively on the type of vibron and is strongly sample dependent. The coupling strength becomes particularly strong when inhomogeneity-induced electronic q...

Plasmon-Mediated Electron Transport in Tip-Enhanced Raman Spectroscopic Junctions.

We combine experiment, theory, and first-principles-based calculations to study the light-induced plasmon-mediated electron transport characteristics of a molecular-scale junction. The experimental data show a nonlinear increase in electronic current perturbation when the focus of a chopped laser beam moves laterally toward the tip-sample junction. To understand this behavior and generalize it,...